Accession Number : AD0701701

Title :   INTERACTION OF BORON TRIHALIDES WITH HEXAFLUOROACETONE IMINE,

Corporate Author : KENTUCKY UNIV LEXINGTON DEPT OF CHEMISTRY

Personal Author(s) : Niedenzu,Kurt ; Blick,Kenneth E. ; Miller,Clifford D.

Report Date : DEC 1969

Pagination or Media Count : 9

Abstract : Boron trifuluoride forms a 1:1 addition compound with (CF3)2CNH. In contrast, BCl3 and BBr3 add across the CN double bond of the imine to yield (CF3)2CX-NH-BX2 derivatives. The structure of these aminoboranes was verified by vibrational spectroscopy. (Author)

Descriptors :   (*IMINES, *ADDITION REACTIONS), (*BORANES, *INFRARED SPECTRA), HALOGENATED HYDROCARBONS, FLUORINE COMPOUNDS, CHLORIDES, SYNTHESIS(CHEMISTRY)

Subject Categories : Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE