Accession Number : AD0701717

Title :   ADVANCED OXIDIZER CHEMISTRY.

Descriptive Note : Final rept. 1 Jan 68-31 Dec 69,

Corporate Author : IIT RESEARCH INST CHICAGO ILL

Personal Author(s) : Solomon,Irvine J.

Report Date : 09 FEB 1970

Pagination or Media Count : 94

Abstract : The reaction of O2F2 with perfluoropropene has been shown to yield two new OOF compounds, CF3CF2CF2OOF and (CF3)2CFOOF. Attempts were made to further characterize O2ClF3. The mechanism of the reaction of COF2 and OF2 in the presence of CsF was studied using O17 tracer techniques. A new method of perparation of CF3OOF is discussed. The reaction of CF3COF and OF2 is also discussed. A study of the reaction of O4F2 has shown it to be a better source of the OOF radical than O2F2. Papers are included on the following subjects: 'Additional studies concerning the existence of 'O3F2',' 'The reaction of dioxygen difluoride and perfluoropropene. Preparation of 1-fluoroperoxyperfluoropropane 2-fluoroperoxyperfluoropropane,' 'The reaction of O4F2 and sulfur dioxide,' 'The preparation of fluoroperoxytrifluoromethane. The mechanism of the reaction of oxygen difluoride and carbonyl fluoride,' 'The reaction of dioxygen difluoride and sulfur oxides and with sulfur oxyfluorides,' 'The chemistry and structure of dioxygenyl fluoroborate. Fluorine-18 tracer studies and decomposition kinetics,' 'The reaction of oxygen difluoride and sulfur trioxide. Transfer of the OF radical,' 'The reaction of dioxygen difluoride and sulfur dioxide. Transfer of the OOF group,' 'Indirect determination of fluorides by the EDTA titration of Samarium.' (Author)

Descriptors :   (*OXYGEN, *FLUORINATION), (*FLUORIDES, *OXIDIZERS), (*HALOGENATED HYDROCARBONS, *OXIDATION), (*VOLUMETRIC ANALYSIS, FLUORIDES), FLUORINE, ORGANIC COMPOUNDS, CHEMICAL REACTIONS, NUCLEAR MAGNETIC RESONANCE, CESIUM COMPOUNDS, PEROXIDES, SULFUR COMPOUNDS, DIOXIDES

Subject Categories : Inorganic Chemistry
      Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE