Accession Number : AD0702088

Title :   NOVEL CHELATED BISCARBORANE TRANSITION METAL COMPLEXES FORMED THROUGH CARBON-METAL SIGMA BONDS.

Descriptive Note : Technical rept.,

Corporate Author : CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY

Personal Author(s) : Owen,David O. ; Hawthorne,M. Frederick

Report Date : 28 JAN 1970

Pagination or Media Count : 12

Abstract : A series of square planar and tetrahedral complexes have been prepared which contain the bidentate bis-carborane ligand sigma-bonded through carbon to a transition metal. These complexes of B1OC2H1O(-), dodecahydrodicarba-closo-borate (-1), exhibit unusual thermal and chemical stabilities. (Author)

Descriptors :   (*BORANES, COMPLEX COMPOUNDS), (*BORATES, SYNTHESIS(CHEMISTRY)), TRANSITION METALS, INFRARED SPECTRA, NUCLEAR MAGNETIC RESONANCE, COPPER COMPOUNDS, NICKEL COMPOUNDS, COBALT COMPOUNDS

Subject Categories : Inorganic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE