Accession Number : AD0703101

Title :   THE CHEMISTRY OF ALIPHATIC UNCONJUGATED NITRAMINES. III. THERMAL, ELECTROPHILIC, AND NUCLEOPHILIC REACTIONS,

Corporate Author : DEFENCE STANDARDS LABS MARIBYRNONG (AUSTRALIA)

Personal Author(s) : Stals,J.

Report Date : 17 JUL 1969

Pagination or Media Count : 12

Abstract : The VESCF(BJ)-MO electronic bond energies, charge distributions, bond orders, free valencies, and frontier orbital charges, when used as reactivity indices, provide a nucleophilic substitution reactions of nitramide and primary and secondary aliphatic nitramines. A good account of the chemistry of RDX and HMX is also given by the calculated parameters for s- and as N,N- dimethylnitramines. (Author)

Descriptors :   (*NITRAMINES, *CHEMICAL BONDS), (*RDX, MOLECULAR ORBITALS), (*HMX, *MOLECULAR ORBITALS), CHEMICAL REACTIONS, MOLECULAR ASSOCIATION, DIPOLE MOMENTS, AUSTRALIA

Subject Categories : Ammunition and Explosives
      Atomic and Molecular Physics and Spectroscopy

Distribution Statement : APPROVED FOR PUBLIC RELEASE