Accession Number : AD0704299

Title :   HALOGENATED WITH N-HALOAMINES IN STRONG ACIDS. I. THE NATURE OF THE CHAIN PROPAGATING RADICAL,

Corporate Author : NATIONAL RESEARCH COUNCIL OF CANADA OTTAWA (ONTARIO) DIV OF CHEMISTRY

Personal Author(s) : Spanswick,J. ; Ingold,K. U.

Report Date : 08 SEP 1969

Pagination or Media Count : 9

Abstract : The N-haloamine halogenation of 1-chlorobutane in 4 M sulfuric acid in acetic acid as solvent is a radical chain process in which aminium radicals are the principal hydrogen atom abstracting species. With N-chloroamines, a concurrent chlorine atom chain is promoted by impurities such as molecular chlorine, hydrogen chloride, and chloride ion. (Author)

Descriptors :   (*HYDROCARBONS, *CHLORINATION), FREE RADICALS, CHLORINE COMPOUNDS, AMINES, HALOGENATED HYDROCARBONS

Subject Categories : Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE