Accession Number : AD0704301

Title :   CONDENSATION OF SOME SUBSTITUTED PHENOLS AND ANILINES WITH FORMALDEHYDE. FORMATION OF 2-PHENYL-1,3-BENZOXAZINES AND N-(2-HYDROXYBENZYL)-ANILINES.

Corporate Author : NATIONAL RESEARCH COUNCIL OF CANADA OTTAWA (ONTARIO) DIV OF CHEMISTRY

Personal Author(s) : Horswill,E. C. ; Lindsay,D. A. ; Ingold,K. U.

Report Date : 18 SEP 1969

Pagination or Media Count : 6

Abstract : The formalin condensation of 2,4-di-t-butylphenol and 2,4-di-t-butylaniline yields a benzoxazine which, on hydrolysis, gives a hydroxybenzylaniline. In contrast to earlier studies the condensation of equimolar quantities of 4-t-butylphenol, o-toluidine, and formaldehyde yields N-(2-hydroxy-5-t-butylbenzyl)-o-toluidine, rather than 2-amino-3-methyl-2'-hydroxy-5'-butyldiphenylmethane. (Author)

Descriptors :   (*PHENOLS, *CONDENSATION REACTIONS), AMINES, SYNTHESIS(CHEMISTRY), CANADA

Subject Categories : Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE