Accession Number : AD0705769

Title :   EMPIRICAL CORRELATIONS OF MOLECULAR CONSTANTS FOR CARBON-CARBON, CARBON-NITROGEN, CARBON-OXYGEN, NITROGEN-NITROGEN, NITROGEN-OXYGEN AND OXYGEN-OXYGEN BONDS,

Corporate Author : MELBOURNE UNIV PARKVILLE (AUSTRALIA) DEPT OF CHEMISTRY

Personal Author(s) : Stals,J.

Report Date : 1969

Pagination or Media Count : 22

Abstract : The molecular constants considered in this paper are the bond length (l), the bond order and overlap population (P), the quadratic stretch-stretch force constant (f), and the bond dissociation energy (D). Briefly reviewed are the different types of l, P, f and D values in present use, chosen a consistent set of equations for their correlation and evaluated the empirical constants present in these equations, from a set of standard molecules for each bond-type, for which accurate experimental values of l, P, f and D were available.

Descriptors :   (*MOLECULES, *CHEMICAL BONDS), POLYATOMIC MOLECULES, MOLECULAR ORBITALS, AUSTRALIA

Subject Categories : Atomic and Molecular Physics and Spectroscopy

Distribution Statement : APPROVED FOR PUBLIC RELEASE