
Accession Number : AD0707422
Title : DISSOCIATIVE PROBABILITIES FOR SQUARE WELL OSCILLATORS,
Corporate Author : BOSTON COLL CHESTNUT HILL MASS DEPT OF CHEMISTRY
Personal Author(s) : Valance,W. G. ; Lin,J. L.
Report Date : MAY 1970
Pagination or Media Count : 14
Abstract : Bound to continuum transition probability for a square well oscillator under a collinear collision with an inert gas atom is derived using the first order time dependent perturbation theory. The continuum wave function of the oscillator is quantized by the method of box normalization. The theory is applied to the system He + H2 to compute the dissociative probability as a function of total energy. This result is then discussed in relation to the dissociation of diatomic molecules. (Author)
Descriptors : (*DIATOMIC MOLECULES, *DISSOCIATION), (*HYDROGEN, DISSOCIATION), OSCILLATION, WAVE FUNCTIONS, HELIUM
Subject Categories : Physical Chemistry
Distribution Statement : APPROVED FOR PUBLIC RELEASE