Accession Number : AD0707784
Title : THE PYROLYSIS OF TETRAFLUOROHYDRAZINE.
Descriptive Note : Technical rept.,
Corporate Author : GEORGE WASHINGTON UNIV WASHINGTON D C DEPT OF CHEMISTRY
Personal Author(s) : Levy,Joseph B. ; Corbin,Warren N.
Report Date : 01 JUN 1970
Pagination or Media Count : 27
Abstract : The pyrolysis of tetrafluorohydrazine was studied in a passivated monel bulb over the temperature range 315-520C and at pressures from about 30-700 torr. The stoichiometry was confirmed by gas chromatographic analysis, and the reaction kinetics investigated manometrically and analytically. 6NF2 yields 4NF3 + N2. The reaction rate was found to exhibit good second order behavior at temperatures above 405C. Evidence is presented that the reaction is homogeneous and the mechanism is bimolecular. (Author)
Descriptors : (*HYDRAZINE DERIVATIVES, *PYROLYSIS), (*FLUORINE COMPOUNDS, PYROLYSIS), GAS CHROMATOGRAPHY, REACTION KINETICS, FLUOROAMINES, THERMOCHEMISTRY
Subject Categories : Inorganic Chemistry
Distribution Statement : APPROVED FOR PUBLIC RELEASE