Accession Number : AD0707784

Title :   THE PYROLYSIS OF TETRAFLUOROHYDRAZINE.

Descriptive Note : Technical rept.,

Corporate Author : GEORGE WASHINGTON UNIV WASHINGTON D C DEPT OF CHEMISTRY

Personal Author(s) : Levy,Joseph B. ; Corbin,Warren N.

Report Date : 01 JUN 1970

Pagination or Media Count : 27

Abstract : The pyrolysis of tetrafluorohydrazine was studied in a passivated monel bulb over the temperature range 315-520C and at pressures from about 30-700 torr. The stoichiometry was confirmed by gas chromatographic analysis, and the reaction kinetics investigated manometrically and analytically. 6NF2 yields 4NF3 + N2. The reaction rate was found to exhibit good second order behavior at temperatures above 405C. Evidence is presented that the reaction is homogeneous and the mechanism is bimolecular. (Author)

Descriptors :   (*HYDRAZINE DERIVATIVES, *PYROLYSIS), (*FLUORINE COMPOUNDS, PYROLYSIS), GAS CHROMATOGRAPHY, REACTION KINETICS, FLUOROAMINES, THERMOCHEMISTRY

Subject Categories : Inorganic Chemistry
      Physical Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE