Accession Number : AD0710281
Title : HYBRIDIZATION FROM VIBRATIONAL FORCE CONSTANTS.
Descriptive Note : Final rept. 1 May 66-30 Apr 70,
Corporate Author : ROCKETDYNE CANOGA PARK CALIF
Personal Author(s) : Curtis,E. C.
Report Date : 30 APR 1970
Pagination or Media Count : 20
Abstract : A summary is given on force constant computations on some small inorganic molecules. The molecules considered were selected largely from the interhalogens, the noble gas compounds and some related molecules. When possible, the numerical force constants were analyzed in terms of models related to the type of molecular bonds. A method was developed to permit analysis of underdetermined systems in a statistically sound fashion. While this does not permit a unique solution, it conveniently requires that force constants for similar molecules be transferable and provides an uncertainty estimate. This method was appropriate for a number of the cases considered. (Author)
Descriptors : (*POLYATOMIC MOLECULES, *MOLECULAR ENERGY LEVELS), CHEMICAL BONDS, BROMINE COMPOUNDS, FLUORIDES, OXYGEN COMPOUNDS, VIBRATION, CHLORINE COMPOUNDS
Subject Categories : Atomic and Molecular Physics and Spectroscopy
Distribution Statement : APPROVED FOR PUBLIC RELEASE