Accession Number : AD0710757

Title :   SYNTHESIS AND REACTIONS OF NOVEL BRIDGED DICARBOLLIDE COMPLEXES HAVING ELECTRON DEFICIENT CARBON ATOMS.

Descriptive Note : Technical rept.,

Corporate Author : CALIFORNIA UNIV RIVERSIDE DEPT OF CHEMISTRY

Personal Author(s) : Francis,James N. ; Hawthorne,M. Frederick

Report Date : 03 AUG 1970

Pagination or Media Count : 19

Abstract : Reaction of the bis-pi-dicarbollide ligand complexes of Co(+3) and Fe(+3) with CS2 in the presence of AlCl3 and HCl produced the firts examples of zwitterionic species having an -S-CH(+)-S- bridge between boron atoms of the two dicarbollide ion ligands of the complex. Similarly, a suspected -OC(CH3)(+)O- bridged species results from the reaction of acetic acid/acetic anhydride with an HClO4 catalyst. Further transformations of these species are described. (Author)

Descriptors :   (*BORON COMPOUNDS, SYNTHESIS(CHEMISTRY)), (*COBALT COMPOUNDS, SYNTHESIS(CHEMISTRY)), (*BORATES, CHEMICAL REACTIONS), IONS, COMPLEX COMPOUNDS, SULFIDES

Subject Categories : Inorganic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE