Accession Number : AD0710758

Title :   SYNTHESIS AND PROPERTIES OF COBALT COMPLEXES CONTAINING THE BIDENTATE pi-BONDING B8C2H10(-4) LIGAND.

Descriptive Note : Technical rept.,

Corporate Author : CALIFORNIA UNIV RIVERSIDE DEPT OF CHEMISTRY

Personal Author(s) : Francis,James N. ; Hawthorne,M. Frederick

Report Date : 03 AUG 1970

Pagination or Media Count : 19

Abstract : The reaction of bis-(pi-(3)-1,2-B9C2H11)2Co(-1) with aqueous base at 100C and in the presence of added Co(+2) produced (in low yield) two polymetal complexes which contain the bidentate pi-bonding B8C2H10(-4) ion. The preparation and properties of these two complexes, (B9C2H11CoB8C2H10CoB9C2H11)(-2) and (B9C2H11CoB8C2H10CoB8C2H10-CoB9C2H11)(-3) are described. (Author)

Descriptors :   (*BORON COMPOUNDS, SYNTHESIS(CHEMISTRY)), (*COBALT COMPOUNDS, SYNTHESIS(CHEMISTRY)), (*BORATES, CHEMICAL REACTIONS), IONS, COMPLEX COMPOUNDS, INFRARED SPECTRA

Subject Categories : Inorganic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE