Accession Number : AD0712540

Title :   SMALL CARBORANE-METALLOCENE ANALOGS. IRON pi-COMPLEXES CONTAINING THE NIDO-C2B4H6(-2)-AND CYCLO-C2B3H7(-2)-LIGANDS.

Descriptive Note : Technical rept.,

Corporate Author : VIRGINIA UNIV CHARLOTTESVILLE DEPT OF CHEMISTRY

Personal Author(s) : Grimes,Russell N.

Report Date : OCT 1970

Pagination or Media Count : 10

Abstract : New carborane-transition metal pi-complexes involving the nido-C2B4H6(2-) and cyclo-C2B3H7(2-) ligands have been synthesized from iron pentacarbonyl and 2,3-dicarba-closo-hexaborane(8) in a heated tube, and the structures have been assigned on the basis of boron-11 and proton nmr spectra, as well as infrared and mass spectroscopic evidence. (Author)

Descriptors :   (*BORANES, *COMPLEX COMPOUNDS), (*IRON COMPOUNDS, COMPLEX COMPOUNDS), MOLECULAR STRUCTURE, NUCLEAR MAGNETIC RESONANCE, METAL CARBONYLS, INFRARED SPECTRA, MASS SPECTRA

Subject Categories : Inorganic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE