Accession Number : AD0712718

Title :   STUDIES IN STEREOCHEMISTRY.

Descriptive Note : Final rept. 1 Aug 68-31 Aug 70,

Corporate Author : PRINCETON UNIV N J DEPT OF CHEMISTRY

Personal Author(s) : Mislow,Kurt

Report Date : 24 SEP 1970

Pagination or Media Count : 17

Abstract : Brief summaries are presented on stereochemical research on the following topics: Synthesis and configuration of phosphine oxides; Hexachlorodisilane: A novel reducing agent for organic oxides and sulfides; Optical purity of phosphines by NMR; Pseudorotation and the stereochemistry of displacement reactions; Stereomutation of phosphine oxides by lithium aluminum hydride; Optical rotatory power; (2,3)-Sigmatropic rearrangements; and Energy barriers in pyramidal inversion process.

Descriptors :   (*PHOSPHINES, *STEREOCHEMISTRY), PHOSPHINE OXIDES, REDUCTION(CHEMISTRY), SILANES, MOLECULAR ROTATION

Subject Categories : Inorganic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE