Accession Number : AD0714020

Title :   Unimolecular Decomposition and Intramolecular Energy Relaxation in the supra High Pressure Region.

Descriptive Note : Technical rept.,

Corporate Author : WASHINGTON UNIV SEATTLE DEPT OF CHEMISTRY

Personal Author(s) : Rabinovitch,B. S. ; Oref,I. ; Schuetzle,D.

Report Date : 01 OCT 1970

Pagination or Media Count : 18

Abstract : The study of the unimolecular decomposition of chemically activated butyl-2 radicals was extended to over 200 atm. of bath gas (H2) pressure. No evidence for failure of the internal energy randomization postulate is evident in this system at a mean time between collisions of 2 x 10 to the -13th sec. (Author)

Descriptors :   (*FREE RADICALS, *DECOMPOSITION), BUTANES, REACTION KINETICS, HEAT OF ACTIVATION

Subject Categories : Physical Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE