Accession Number : AD0714020
Title : Unimolecular Decomposition and Intramolecular Energy Relaxation in the supra High Pressure Region.
Descriptive Note : Technical rept.,
Corporate Author : WASHINGTON UNIV SEATTLE DEPT OF CHEMISTRY
Personal Author(s) : Rabinovitch,B. S. ; Oref,I. ; Schuetzle,D.
Report Date : 01 OCT 1970
Pagination or Media Count : 18
Abstract : The study of the unimolecular decomposition of chemically activated butyl-2 radicals was extended to over 200 atm. of bath gas (H2) pressure. No evidence for failure of the internal energy randomization postulate is evident in this system at a mean time between collisions of 2 x 10 to the -13th sec. (Author)
Descriptors : (*FREE RADICALS, *DECOMPOSITION), BUTANES, REACTION KINETICS, HEAT OF ACTIVATION
Subject Categories : Physical Chemistry
Distribution Statement : APPROVED FOR PUBLIC RELEASE