Accession Number : AD0714256

Title :   Effect of DC Polarographic Maxima on AC Waves.

Descriptive Note : Research rept.,

Corporate Author : KENTUCKY UNIV LEXINGTON DEPT OF CHEMISTRY

Personal Author(s) : Hawkridge,F. M. ; Bauer,H. H.

Report Date : OCT 1970

Pagination or Media Count : 13

Abstract : The presence of a maximum on the d.c. polarographic curve does not preclude the possibility of a.c. studies of kinetics and mechanisms or of analytical determinations by a.c. polarography in absence of maximum suppressors. A necessary condition is that 3-electrode circuitry with potentiostatic control of the working electrode be used. The a.c. process is affected much less (if at all) than is the d.c. by the streaming that accompanies maximum formation. (Author)

Descriptors :   (*POLAROGRAPHIC ANALYSIS, *ELECTROCHEMISTRY), COPPER, OXIDATION REDUCTION REACTIONS, ELECTRODES, ELECTRICAL IMPEDANCE

Subject Categories : Physical Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE