Accession Number : AD0714867

Title :   Preparation and Reactions of a Dicarba-nido-decaborane(12).

Descriptive Note : Technical rept.,

Corporate Author : CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY

Personal Author(s) : Hawthorne,M. Frederick ; Garrett,Philip M. ; Ditta,Gary S.

Report Date : 05 NOV 1970

Pagination or Media Count : 16

Abstract : Reaction of B7C2H11(-2) with B2H6 affords NaBH4, H2, 1,6B8C2H10 and a new nido-carborane B8C2H12. Reactions of B8C2H12 include chlorination by HCl, amine addition and thermal conversion to 1,6-B8C2H10 and H2 in quantitative yield. Topological and structural data are discussed on the basis of 11B nmr spectra (80 MHz). (Author)

Descriptors :   (*BORON COMPOUNDS, SYNTHESIS(CHEMISTRY)), MOLECULAR STRUCTURE, NUCLEAR MAGNETIC RESONANCE, AMINES, DIBORANES

Subject Categories : Inorganic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE