Accession Number : AD0717079

Title :   Research in NF Compounds.

Descriptive Note : Annual rept. 1 Dec 68-1 Dec 69,

Corporate Author : AEROJET-GENERAL CORP EL MONTE CALIF ENVIRONMENTAL SYSTEMS DIV

Personal Author(s) : Baum,K. ; Grakauskas,V.

Report Date : JAN 1970

Pagination or Media Count : 79

Abstract : Gem-diperchlorates were obtained by the reaction of ketones with anhydrous perchloric acid in halogenated solvents. Cyclohexene was reduced to cyclohexane by perchloric acid in chloroform. Isopropyl chlorofluorocarbamate and bromofluorocarbamate added to olefins and acted as halogenating agents toward hydrcarbons by free radical chain mechanisms involving fluoraminocarboalkoxy free radicals. Isopropyl fluorocarbamate and mercuric oxide gave bis(carboisopropoxyfluoramino)mercury. The latter was found to add to olefins. The following phases of earlier research were completed and the work was assembled in the form of manuscripts: (1) Direct fluorination of ureas, (2) Direct fluorination of amides, and (3) Synthesis of alpha,alpha-dinitro-N'-fluorodiimide N-oxides. (Author)

Descriptors :   (*PERCHLORATES, SYNTHESIS(CHEMISTRY)), (*CARBAMIC ACID, CHEMICAL REACTIONS), (*ALKENES, *ADDITION REACTIONS), (*UREA, *FLUORINATION), (*AMIDES, FLUORINATION), FLUOROAMINES, HALOGENATED HYDROCARBONS, NUCLEAR MAGNETIC RESONANCE, FLUORINE COMPOUNDS

Subject Categories : Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE