Accession Number : AD0718385

Title :   Nuclear Magnetic Resonance Evidence for Bridge Hydrogen Tautomerization (and/or Exchange) in Monocarbahexaborane(7).

Descriptive Note : Interim technical rept.,

Corporate Author : CALIFORNIA STATE COLL LOS ANGELES DEPT OF CHEMISTRY

Personal Author(s) : Onak,Thomas ; Leach,John B.

Report Date : JAN 1971

Pagination or Media Count : 10

Abstract : Temperature studies on monocarbahexaborane(7) show that the two high field doublets in the boron-11 n.m.r. taken at +30C collapse into a single doublet at 100C. Possible mechanisms are proposed to account for this observation but all involve migration of the single bridge hydrogen. (Author)

Descriptors :   (*BORANES, *NUCLEAR MAGNETIC RESONANCE), CHEMICAL BONDS, MOLECULAR STRUCTURE

Subject Categories : Inorganic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE