Accession Number : AD0721130

Title :   Tris(trifluoromethyl)bis(trimethylsiloxy)phosphorane, (CF3)3P(OSi(CH3)3)2, and Bis(trifluoromethyl)trimethylsiloxyphosphine Oxide, (CF3)2P(O)OSi(CH3)3,

Corporate Author : ALBERTA UNIV EDMONTON DEPT OF CHEMISTRY

Personal Author(s) : Cavell,R. G. ; Leary,R. D.

Report Date : 10 AUG 1970

Pagination or Media Count : 3

Abstract : Direct combination of (CF3)3PO with hexamethyldisiloxane yields the new phosphorane (CF3)3P(OSiMe3)2 which thermally decomposes to (CF3)2P(O)-OSiMe3; the latter new compound can also be obtained by reaction of (CF3)2P(O)Cl with hexamethyldisiloxane. (Author)

Descriptors :   (*ORGANIC PHOSPHORUS COMPOUNDS, SYNTHESIS(CHEMISTRY)), HALOGENATED HYDROCARBONS, FLUORINE COMPOUNDS, SILANES

Subject Categories : Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE