Accession Number : AD0721177

Title :   Acid-Base Equilibria and Titrations and Electrochemical Equilibria in Acetonitrile.

Descriptive Note : Final scientific rept. 1 Oct 66-28 Feb 71,

Corporate Author : MINNESOTA UNIV MINNEAPOLIS DEPT OF CHEMISTRY

Personal Author(s) : Koltoff,I. M.

Report Date : MAR 1971

Pagination or Media Count : 7

Abstract : Very briefly discussed are studies which have been made of acid-base equilibria and titrations and also of conjugation in acetonitrile (AN) as a solvent. Dissociation constants of a host of uncharged and cationic acids have been determined, including acid-base indicators. The protonation constants of water, methanol, butanol and diethylether in AN have been determined. The heteroconjugation constants of sulfate and bisulfate ions in AN with uncharged hydrogen bond donors have been determined. (Author)

Descriptors :   (*ACETONITRILE, *ACID BASE EQUILIBRIUM), (*ORGANIC SOLVENTS, ACETONITRILE), ELECTROCHEMISTRY, MOLECULAR ASSOCIATION, COMPLEX COMPOUNDS

Subject Categories : Atomic and Molecular Physics and Spectroscopy

Distribution Statement : APPROVED FOR PUBLIC RELEASE