Accession Number : AD0724706

Title :   Studies of Electrochemical Processes.

Descriptive Note : Annual technical rept. no. 1,

Corporate Author : KENTUCKY UNIV LEXINGTON DEPT OF CHEMISTRY

Personal Author(s) : Bauer,H. H. ; Brown,E. V. ; Bradley,E. B. ; Bruner,B. L. ; Christian,G. D.

Report Date : SEP 1970

Pagination or Media Count : 112

Abstract : Salting effects are reported for 1-butanol, 1-pentanol, and cyclohexanol in KF, KCl, NaClO4 and Na2SO4. Adsorption-desorption potentials in these systems are interpreted in terms of specific adsorption of the electrolyte and competition with the surface-active alcohols. Bipyridyls have been prepared electrochemically from picolinic acid, nicotinic acid, and isonicotinic acid. Some of the isomeric pinacols have been obtained from phenyl-quinolyl ketones. Voltammetric analysis of ferrate(VI) has been studied. Conductance and viscosity of Bu4NI, KSCN, and NH4Br have been measured in N,N-dimethylformamide. Novel B, N, F compounds have been prepared as starting materials for electrochemical studies. (Author)

Descriptors :   (*ALCOHOLS, *ADSORPTION), (*FERRATES, ELECTROCHEMISTRY), (*AMMONIUM COMPOUNDS, ELECTRICAL CONDUCTIVITY), (*ELECTROCHEMISTRY, ALCOHOLS), BUTANOLS, PENTANOLS, SOLUTIONS(MIXTURES), SALTS, ELECTROLYTES, BORANES, HALOGENATED HYDROCARBONS, FLUORINE COMPOUNDS, AMINES, THIOCYANATES

Subject Categories : Organic Chemistry
      Physical Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE