Accession Number : AD0728702

Title :   The Kinetics of Successive Aquation Reactions of Tetraamminepalladium(II) Ion.

Descriptive Note : Master's thesis,

Corporate Author : NAVAL POSTGRADUATE SCHOOL MONTEREY CALIF

Personal Author(s) : DeBerry,William Jennings , Jr

Report Date : JUN 1971

Pagination or Media Count : 91

Abstract : Solutions of tetraamminepalladium(II) perchlorate were made up and analyzed. Acid hydrolysis reactions of tetraamminepalladium(II) ion were studied by ultraviolet spectroscopy. First order rate constants were evaluated for each step of the reaction series at various temperatures. Activation parameters were determined. Mechanisms for the consecutive reactions are proposed, and cis and trans effects are discussed. (Author)

Descriptors :   (*PALLADIUM COMPOUNDS, *HYDROLYSIS), COMPLEX COMPOUNDS, ULTRAVIOLET SPECTROSCOPY, REACTION KINETICS, HYDRATES, THESES

Subject Categories : Inorganic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE