Accession Number : AD0735926

Title :   Sigmi-Bonded Complexes of Substituted Phospha- and Arsacarboranes and Their Pi-Ollyl Derivatives.

Descriptive Note : Technical rept.,

Corporate Author : INDIANA UNIV BLOOMINGTON DEPT OF CHEMISTRY

Personal Author(s) : Todd,L. J. ; Beer,D. C.

Report Date : JAN 1972

Pagination or Media Count : 28

Abstract : The photochemical reaction of (1,7-B9H9CHE)2Fe(2-) (E = P or As) with group VI metal carbonyls lead to the formation of complexes with the general formula, (1,7-B9H9CHE:M(CO)5)2Fe(2-). It is proposed that each heteroatom carborane ligand is pi - bonded to the iron atom and sigma - bonded through either the phosphorus or arsenic atom to a group VI metal carbonyl. The preparation and characterization of a neutral phosphacarborane sigma - complex is described. (Author)

Descriptors :   (*BORON COMPOUNDS, *COMPLEX COMPOUNDS), (*PHOTOCHEMICAL REACTIONS, *BORATES), (*METAL CARBONYLS, PHOTOCHEMICAL REACTIONS), IRON COMPOUNDS, PHOSPHORUS COMPOUNDS, ARSENIC, SYNTHESIS(CHEMISTRY), MASS SPECTRA, INFRARED SPECTRA

Subject Categories : Inorganic Chemistry
      Radiation and Nuclear Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE