Accession Number : AD0738490

Title :   Kinetics of Synthesis and Decomposition Reactions of Ionic Compounds Containing N-F Cations.

Descriptive Note : Annual summary rept. no. 4 1 Feb 71-31 Jan 72,

Corporate Author : IIT RESEARCH INST CHICAGO ILL

Personal Author(s) : Solomon,Irvine J. ; Keith,James N.

Report Date : 28 FEB 1972

Pagination or Media Count : 37

Abstract : Kinetic studies indicate that NF4AsF6 decomposes via an equilibrium dissociation NF4AsF6 = NF5 + AsF5 followed by a rapid fractional order reaction: NF5 = NF3 + F2. Attempts to identify NF5 in the decomposition products were inconclusive. Also discussed but very briefly are results on the reaction of bromine dioxide (probably containing some BrO3) with O2F2, as well as the preparation of NH3FCl04 from N-fluoriosopropyl carbamate and perchloric acid. (Author)

Descriptors :   (*AMMONIUM COMPOUNDS, *PYROLYSIS), (*ARSENIC COMPOUNDS, PYROLYSIS), REACTION KINETICS, ARSENIC COMPOUNDS, FLUORIDES, BROMINE COMPOUNDS, PERCHLORATES, OXIDES, SALTS

Subject Categories : Inorganic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE