Accession Number : AD0742484

Title :   Rubber Research. The Synthesis of Unsaturated Fluorocarbons.

Descriptive Note : Progress rept. No. 9, 13 Aug-13 Nov 60,

Corporate Author : COLORADO UNIV BOULDER

Personal Author(s) : Park,J. D. ; Lacher,J. R.

Report Date : 10 DEC 1960

Pagination or Media Count : 11

Abstract : The report describes the synthesis of CF2Cl-CF2NO using NOCl and FeCl3 as a catalyst. The FeCl3 also forms an addition complex with the nitorso compound. The compound, UO2(NO3)2:H2O:N2O4, was used to nitrate CF2=CFCl as a means of producing nitroso compounds by stopping the reaction before completion. The reduction of fluoronitro alkanes was also tried. As a precursor to imine synthesis, CF3-CF2-CF2-CHOH-CH2NO2 was prepared.

Descriptors :   (*HALOGENATED HYDROCARBONS, SYNTHESIS(CHEMISTRY)), (*NITROSO COMPOUNDS, SYNTHESIS(CHEMISTRY)), FLUORINE COMPOUNDS, CHLORINE COMPOUNDS, CATALYSTS, IRON COMPOUNDS, COMPLEX COMPOUNDS, URANIUM COMPOUNDS, NITRATES, NITRATION, REDUCTION(CHEMISTRY), IMINES

Subject Categories : Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE