Accession Number : AD0742850

Title :   Inorganic Halogen Oxidizer Research.

Descriptive Note : Annual rept. 1 Apr 71-31 Mar 72,

Corporate Author : ROCKETDYNE CANOGA PARK CALIF

Personal Author(s) : Pilipovich,Donald ; Wilson,Richard D. ; Christe,Karl O. ; Curtis,Earl C. ; Schack,Carl J.

Report Date : 26 MAY 1972

Pagination or Media Count : 150

Abstract : A summary of the authors' research on inorganic halogen oxidizers is presented. Also given are full discussions on the following: The difluoroperchloryl cation, ClO2F2(+); Chlorine Trifluoride dioxide, ClF3O2; The hexafluorochlorine (VII) cation, ClF6(+); On the reactions of chlorine fluorides with hydroxyl compounds; Iodine trisperchlorate and cesium tetraperchlorato iodate (III); On alkali metal fluoride - IF5 adducts; The tetrafluoroidate (III) anion, IF4(-); A fluorine-19 nmr study of chlorine fluoride cations; Chlorine trifluoride oxide, vibrational spectrum, force constants, and thermodynamic properties; The tetrafluorooxychlorate (V) anion, ClF4O(-), vibrational spectra and force constants. (Author)

Descriptors :   (*HALOGEN COMPOUNDS, CHEMICAL PROPERTIES), (*OXIDIZERS, HALOGEN COMPOUNDS), (*CHLORINE COMPOUNDS, CHEMICAL PROPERTIES), SCIENTIFIC RESEARCH, FLUORIDES, IONS, IODATES, OXIDES, CHLORATES, SYNTHESIS(CHEMISTRY), NITRIC ACID, WATER, CESIUM COMPOUNDS, INFRARED SPECTRA, THERMODYNAMICS, MOLECULAR STRUCTURE, NUCLEAR MAGNETIC RESONANCE

Subject Categories : Inorganic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE