Accession Number : AD0750281

Title :   Theoretical Rate Constants for the Formation and Decomposition of Chlorinated Ethyl Radicals.

Descriptive Note : Technical rept.,

Corporate Author : WASHINGTON UNIV SEATTLE DEPT OF CHEMISTRY

Personal Author(s) : Skinner,Gordon B. ; Rabinovitch,B. S.

Report Date : 10 OCT 1972

Pagination or Media Count : 30

Abstract : The rates of decomposition have been calculated for the series of chemically activated chloroethyl radicals, C2H(x)Cl(5-x). It was found that, apart from some discrepancies that appear to be experimental error, the calculated and observed literature values are in good agreement and support the usefulness of RRKM theory. (Author)

Descriptors :   (*FREE RADICALS, *DECOMPOSITION), (*HALOGENATED HYDROCARBONS, FREE RADICALS), THEORY, CHLORINE COMPOUNDS, REACTION KINETICS, COMPLEX COMPOUNDS, MATHEMATICAL ANALYSIS, CHEMICAL BONDS, HEAT OF ACTIVATION

Subject Categories : Physical Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE