Accession Number : AD0750282

Title :   Reactions of Bis(pentafluoroselenium) Peroxide: Synthesis of Pentafluoroselenium Fluorosulfate and of Bis(pentafluoroselenium) Oxide.

Descriptive Note : Technical rept.,

Corporate Author : WASHINGTON UNIV SEATTLE DEPT OF CHEMISTRY

Personal Author(s) : Reichert,William L. ; Cady,George H.

Report Date : OCT 1972

Pagination or Media Count : 19

Abstract : When SeF5OOSeF5 is produced by the reaction of fluorine with selenium dioxide a substantial proportion of SeF5OSeF5 is also formed. Bis(pentafluoroselenium) oxide is relatively stable and resists hydrolysis. The new compound, pentafluoroselenium fluorosulfate (SeF5OSO2F), is produced by the reaction of SeF5OOSeF5 with peroxydisulfuryl difluoride (S2O6F2). (Author)

Descriptors :   (*SELENIUM COMPOUNDS, SYNTHESIS(CHEMISTRY)), PEROXIDES, FLUORIDES, SULFUR COMPOUNDS, OXIDES, INFRARED SPECTRA, NUCLEAR MAGNETIC RESONANCE, ULTRAVIOLET SPECTRA, VISIBLE SPECTRA

Subject Categories : Inorganic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE