Accession Number : AD0752202
Title : The Synthesis and Chemistry of Fluorine-Containing Benezenediazooxides.
Descriptive Note : Technical rept.,
Corporate Author : AIR FORCE MATERIALS LAB WRIGHT-PATTERSON AFB OHIO
Personal Author(s) : Spence,J. W.
Report Date : DEC 1971
Pagination or Media Count : 61
Abstract : The report covers the synthesis of fluorine-containing benezenediazooxides. Compounds of particular interest are tetrafluoro-ortho- and para-benezenediazooxides. Tetrafluoro-ortho- and para-benezenediazooxides were synthesized and characterized by infrared and nuclear magnetic resonance. Triphenylphosphine, beta-naphthol, and N, N-dimethylaniline were found to couple with the tetrafluoro-para-benezenediazooxide; however, attempts to form derivatives of the tetrafluoro-ortho-benezenediazooxide were unsuccessful. Methoxytri-fluoro-1, 4-benezenediazooxide was synthesized from 2, 3, 5, 6-tetrafluoro-para-anisidine. The structure of this diazooxide and the mechanism of reaction are under investigation. (Author)
Descriptors : (*ORGANIC NITROGEN COMPOUNDS, SYNTHESIS(CHEMISTRY)), (*QUINONES, CHEMICAL REACTIONS), HALOGENATED HYDROCARBONS, FLUORINE COMPOUNDS, KETONES, DIENES, NUCLEAR MAGNETIC RESONANCE, MOLECULAR STRUCTURE, INFRARED SPECTRA, NITROBENZENES
Subject Categories : Organic Chemistry
Distribution Statement : APPROVED FOR PUBLIC RELEASE