Accession Number : AD0752202

Title :   The Synthesis and Chemistry of Fluorine-Containing Benezenediazooxides.

Descriptive Note : Technical rept.,

Corporate Author : AIR FORCE MATERIALS LAB WRIGHT-PATTERSON AFB OHIO

Personal Author(s) : Spence,J. W.

Report Date : DEC 1971

Pagination or Media Count : 61

Abstract : The report covers the synthesis of fluorine-containing benezenediazooxides. Compounds of particular interest are tetrafluoro-ortho- and para-benezenediazooxides. Tetrafluoro-ortho- and para-benezenediazooxides were synthesized and characterized by infrared and nuclear magnetic resonance. Triphenylphosphine, beta-naphthol, and N, N-dimethylaniline were found to couple with the tetrafluoro-para-benezenediazooxide; however, attempts to form derivatives of the tetrafluoro-ortho-benezenediazooxide were unsuccessful. Methoxytri-fluoro-1, 4-benezenediazooxide was synthesized from 2, 3, 5, 6-tetrafluoro-para-anisidine. The structure of this diazooxide and the mechanism of reaction are under investigation. (Author)

Descriptors :   (*ORGANIC NITROGEN COMPOUNDS, SYNTHESIS(CHEMISTRY)), (*QUINONES, CHEMICAL REACTIONS), HALOGENATED HYDROCARBONS, FLUORINE COMPOUNDS, KETONES, DIENES, NUCLEAR MAGNETIC RESONANCE, MOLECULAR STRUCTURE, INFRARED SPECTRA, NITROBENZENES

Subject Categories : Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE