Accession Number : AD0754501

Title :   Crystal and Molecular Structure of N-p-Bromobenzoyl-exo-2,3-aziridinobicyclo(2,2,1)heptane,

Corporate Author : NATIONAL RESEARCH COUNCIL OF CANADA OTTAWA (ONTARIO) BIOCHEMISTRY LAB

Personal Author(s) : Gopalakrishna,E. M.

Report Date : 21 MAY 1971

Pagination or Media Count : 6

Abstract : N-p-Bromobenzoyl-exo-2,3-aziridinobicyclo(2,2,1)heptane, BrC6H4CONC7H10, crystallizes in the monoclinic space group. The structure was determined by the heavy-atom method using three-dimensional diffractometer data. The three bond distances in the bicyclo(2,2,1) heptane system, C(1)-C(2), C(2)-C(3)-C(4) with values of 1.497, 1.491 and 1.512 A respectively, are shorter than the unstrained C-C single-bond distance. The bond angle C(1)-C(7)-C(4) in the same heptane system with a value of 95.4 deg is highly strained.

Descriptors :   (*POLYCYCLIC COMPOUNDS, *MOLECULAR STRUCTURE), (*CRYSTAL STRUCTURE, POLYCYCLIC COMPOUNDS), NITROGEN HETEROCYCLIC COMPOUNDS, AMIDES, X RAY DIFFRACTION, CHEMICAL BONDS, CANADA

Subject Categories : Atomic and Molecular Physics and Spectroscopy

Distribution Statement : APPROVED FOR PUBLIC RELEASE