Accession Number : AD0755338
Title : Effects of Trans alpha-Hydroxyl Groups in Alkaline Degradation of Glycosidic Bonds.
Descriptive Note : Forest Service research paper,
Corporate Author : FOREST PRODUCTS LAB MADISON WIS
Personal Author(s) : Rowell,R. M. ; Green,J.
Report Date : 1972
Pagination or Media Count : 10
Abstract : The influence of alpha, beta-dihydroxyl groups in the alkaline hydrolysis of glucosidic bonds is examined. In derivatives of beta-D-glucopyranosides, all hydroxyl groups are trans to each other, and the alkaline elimination of substituted methyl ethers in positions C-2 and C-4 can be explained, in part, by assistance from neighboring trans alpha-hydroxyls. (Author)
Descriptors : (*CARBOHYDRATES, *HYDROLYSIS), (*GLYCOSIDES, HYDROLYSIS), REACTION KINETICS, MOLECULAR STRUCTURE
Subject Categories : Organic Chemistry
Distribution Statement : APPROVED FOR PUBLIC RELEASE