Accession Number : AD0763693

Title :   Phosphinylmethyl Derivatives.

Descriptive Note : Technical rept.,

Corporate Author : PENNWALT CORP KING OF PRUSSIA PA RESEARCH AND DEVELOPMENT DEPT

Personal Author(s) : King,J. P. ; Popoff,I. C. ; Block,B. P.

Report Date : JUN 1971

Pagination or Media Count : 18

Abstract : Diphenylphosphinylmethanol, methylphenylphosphinylmethanol, and dimethylphosphinylmethanol have been prepared by fusion reactions of sodium acetate and the corresponding P, P-disubstituted chloromethylphosphine oxide at elevated temperatures followed by acid hydrolysis. The intermediate phosphinylmethyl acetates have been isolated and characterized. Both infrared and hydrogen nmr results show that there is extensive intramolecular hydrogen bonding in these phosphinylmethanols. (Author)

Descriptors :   (*ORGANIC PHOSPHORUS COMPOUNDS, CHEMICAL REACTIONS), HALOGENATED HYDROCARBONS, CARBINOLS, SYNTHESIS(CHEMISTRY), HYDROLYSIS, PEROXIDES, INFRARED SPECTRA, NUCLEAR MAGNETIC RESONANCE, MOLECULAR ASSOCIATION

Subject Categories : Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE