Accession Number : AD0764115

Title :   The Ammonation of cis-Dichlorodiammine palladium(II).

Descriptive Note : Master's thesis,

Corporate Author : NAVAL POSTGRADUATE SCHOOL MONTEREY CALIF

Personal Author(s) : Atwill,James Richards , Jr

Report Date : JUN 1973

Pagination or Media Count : 61

Abstract : The reaction of cis-dichlorodiamminepalladium(II) with ammonia: cis-Pd(NH3)2Cl2 to Pd(NH3)3Cl(+) to Pd(NH3)4(2+) Pd(NH3)4(+2) was studied over the temperature range 10-21C using ultraviolet spectroscopy. Slow and fast steps are identified and the observed rate constants for these steps were obtained. Using these values, comparisons are drawn with previously reported data. (Modified author abstract)

Descriptors :   (*PALLADIUM COMPOUNDS, CHEMICAL REACTIONS), (*COMPLEX COMPOUNDS, PALLADIUM COMPOUNDS), (*AMMONIA, CHEMICAL REACTIONS), REACTION KINETICS, EXCHANGE REACTIONS, ULTRAVIOLET SPECTROSCOPY, THESES

Subject Categories : Inorganic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE