Accession Number : AD0766336

Title :   A Fluorine-19 NMR Study of Some Fluorotitanium(IV) Complexes. III.

Descriptive Note : Final technical rept. 16 Jan 72-15 Jan 73,

Corporate Author : WITTENBERG UNIV SPRINGFIELD OHIO

Personal Author(s) : Borden,Robert S.

Report Date : FEB 1973

Pagination or Media Count : 32

Abstract : The stereochemistry of a number of titanium (IV) fluoride complexes has been studied by means of low temperature fluorine-19 nmr. The following systems are examined in this technical report: TiF4--TiBr4--2,6-Dimethylpyridine-N-oxide; TiF4--TiCl4--Dioxane; TiF4--TiCl4--Thioxane; TiF4--TiCl4--Dithiane; TiF4--H2O--Chloroacetonitrile; TiF4--H2O--Methylal; TiF4--TiCl4--H2O--1,2-Dimethoxyethane; TiF4--TiBr4--H2O--1,2-Dimethoxyethane; Structural assignments as well as chemical shift and coupling constant data are presented for each observed complex. In the systems involving water, species containing hydroxyl groups could not be detected although hydrolysis was clearly indicated by the formation of a white precipitate. (Author)

Descriptors :   (*TITANIUM COMPOUNDS, *COMPLEX COMPOUNDS), (*NUCLEAR MAGNETIC RESONANCE, FLUORIDES), CHLORIDES, BROMIDES, SOLUTIONS(MIXTURES), MOLECULAR STRUCTURE, WATER, HYDROLYSIS, ACETONITRILE, HETEROCYCLIC COMPOUNDS, STEREOCHEMISTRY, HYDRATES

Subject Categories : Inorganic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE