Accession Number : AD0769029

Title :   Gas Phase Reactions of Fluorine Atoms,

Corporate Author : DALHOUSIE UNIV HALIFAX (NOVA SCOTIA) DEPT OF CHEMISTRY

Personal Author(s) : Pollock,Thomas Long ; Jones,William Ernest

Report Date : 27 DEC 1972

Pagination or Media Count : 9

Abstract : The rate of reaction of F atoms with a series of compounds, CH4, CH3F, CH2F2, CHF3, CHClF2, HCl, CBrF3, NH3, and PH3 has been determined relative to the chemiluminescent reaction F + NO + Ar to FNO* + Ar to FNO + Ar + hv by photometry. The fluorine atoms were produced in a flow system from the fluid mixing of molecular fluorine and nitric oxide diluted with argon. (Author)

Descriptors :   (*FLUORINE, REACTION KINETICS), PHOSPHINE, AMMONIA, CHEMICAL REACTIONS, CHEMILUMINESCENCE, PHOTOCHEMICAL REACTIONS, METHANE, HALOGENATED HYDROCARBONS, FLUORINE COMPOUNDS, BROMINE COMPOUNDS, CHLORINE COMPOUNDS, ATOMS, NITROGEN OXIDES, CANADA

Subject Categories : Physical Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE