Accession Number : AD0770507

Title :   Crossed Molecular Beam Studies of Transition Metal-Oxygen Reactions.

Descriptive Note : Final rept., 1 May 69-31 Aug 73,

Corporate Author : CASE WESTERN RESERVE UNIV CLEVELAND OHIO

Personal Author(s) : Carlson,K. Douglas

Report Date : NOV 1973

Pagination or Media Count : 26

Abstract : A versatile crossed molecular beam scattering apparatus has been designed and constructed to study the gas-phase kinetics of transition metal-oxygen species. The apparatus consists of a compact and adaptable scattering chamber which contains the facilities to produce and monitor both a high temperature metal vapor beam and a permanent gas beam in a high vacuum environment. It is also equipped with a phase-sensitive, mass spectrometric detection system. Preliminary, low-resolution reactive scattering experiments were carried out. The principal results of these exploratory experiments are the following: (1) There is strong forward peaking in the laboratory coordinate system for the (Ba/N2O) system, with about 99% of the reaction exothermicity going into product internal excitation; and (2) there is reactive scattering in the forward direction in the laboratory system for the (Ce/N2O) system. (Modified author abstract)

Descriptors :   *Molecular beams, *Barium, *Cerium, Reaction kinetics, Laboratory equipment, Nitrogen oxides, Chemical reactions, Scattering, Molecules, Detectors, Mass spectrometers, Transition metals, Oxygen

Subject Categories : Physical Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE