Accession Number : AD0774578

Title :   Rotational Isomerism in Propargyl Amine Studied by Raman Spectroscopy,

Corporate Author : NATIONAL RESEARCH COUNCIL OF CANADA OTTAWA (ONTARIO) DIV OF CHEMISTRY

Personal Author(s) : Verma,A. L. ; Bernstein,H. J.

Report Date : 22 JAN 1973

Pagination or Media Count : 5

Abstract : The Raman spectra of HCC CH2NH2 and DCCCH2ND2 reveal the presence of two rotational isomers for which the enthalpy difference has been obtained in the liquid phase. The N-lone-pair-trans conformation has been shown to be the lower energy form. (Modified author abstract)

Descriptors :   *Raman spectra, *Amines, *Alkynes, Enthalpy, Deuterium compounds, Spectrum analysis, Molecular isomerism, Stereochemistry, Canada

Subject Categories : Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE