Accession Number : AD0781195

Title :   Theoretical Study of Dissociative-Recombination Kinetics.

Descriptive Note : Final rept. 30 Oct 72-30 Nov 73,


Personal Author(s) : Michels,H. H.

Report Date : MAY 1974

Pagination or Media Count : 140

Abstract : Calculations have been performed for the chemical kinetics of the dissociative-recombination of an electron and the positive ion of nitric oxide. Electronic wavefunctions have been constructed for selected dissociating states of NO and expectation values of the electronic energy and electronic transition matrix elements have been calculated. The electronic wavefunctions for NO were analyzed to determine those states responsible for dissociative-recombination. Calculations are presented for the dissociative-recombination cross sections as a function of electron energy and vibrational state of molecular ion. These data are also reduced to kinetic rate constants as a function of the electron temperature and ion vibrational temperature, assuming independent Boltzmann distribution functions. (Modified author abstract)

Descriptors :   *Gas ionization, *Electron capture, *Ionosphere, Temperature, Cross sections, Molecular energy levels, Wave functions, Computations, Rates, Nitrogen oxides, Reaction kinetics, Ions, Molecular vibration, Diatomic molecules, Atmospheric chemistry, Mathematical models, Particle collisions, Tables(Data)

Subject Categories : Atmospheric Physics
      Atomic and Molecular Physics and Spectroscopy

Distribution Statement : APPROVED FOR PUBLIC RELEASE