Accession Number : AD0781272

Title :   Electrochemical Processes Associated with Energy Transfer.

Descriptive Note : Final scientific rept.,

Corporate Author : NORTH CAROLINA UNIV CHAPEL HILL DEPT OF CHEMISTRY

Personal Author(s) : Murray,Royce W. ; Reilley,Charles N.

Report Date : 1974

Pagination or Media Count : 11

Abstract : The reported project has had as its main theme study, on a broad front of research, the modes of energy transfer which can accompany electrochemically induced charge-transfer process. Significant aspects of electrochemical techniques, theory, instrumentation, developed during our studies of energy transfer modes have been (1) development of a computer controlled rapid scan stop flow kinetic spectrometer, (2) determination, using this spectrometer, of the kinetics and mechanism of an important and common electrochemical reaction sub-component, the protonation of a radical anion, (3) development of the theory for half-order regeneration reactions, a difficult-to-assess but perhaps common type of anodic electrode process, and (4) description of a new form of metal complex adsorption involving formation of adsorbed two-dimensional crystal phases. (Modified author abstract)

Descriptors :   *Electrochemistry, *Energy transfer, *Charge transfer, Reaction kinetics, Laboratory equipment, Anions, Adsorption, Metal complexes

Subject Categories : Physical Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE