Accession Number : AD0782986

Title :   Structure of the Mercury/Ethylene Carbonate Interface. Part 3. Adsorption of Thiourea,

Corporate Author : GUELPH UNIV (ONTARIO) DEPT OF CHEMISTRY

Personal Author(s) : Fawcett,W. R. ; Mackey,M. D.

Report Date : 13 AUG 1973

Pagination or Media Count : 15

Abstract : The adsorption of thiourea at mercury from ethylene carbonate solutions containing 0.5 KPF6 and varying amounts of thiourea has been studied by measuring the differential capacity of the polarisable interface as a function of potential. The data were analyzed to obtain the surface excess of thiourea as a function of electrode potential and bulk concentration. The parameters characterizing the adsorption isotherm are discussed in terms of the electrostatic model for dipole adsorption by Kir'yanov, Krylov and Damaskin. These parameters are also compared with those obtained previously for the adsorption of thiourea from water, methanol, formamide, and dimethylformamide. (Modified author abstract)

Descriptors :   *Thiourea, *Adsorption, *Mercury, *Interfaces, Dipoles, Isotherms, Canada, Carbonates, Ethylene, Solutions(Mixtures)

Subject Categories : Physical Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE