Accession Number : AD0803791

Title :   SOME UNUSUAL REACTION OF FLUORKETONES (EINIGE UNGEWOHNLICHE REAKTIONEN VON FLUORKETONEN).

Descriptive Note : Unedited rough draft translation,

Corporate Author : FOREIGN TECHNOLOGY DIV WRIGHT-PATTERSON AFB OH

Personal Author(s) : Gambarian, N. P. ; Seifman, J. W. ; Rokhlin, J. M.

Report Date : 07 DEC 1966

Pagination or Media Count : 14

Abstract : Examined are two reactions that are completely foreign to common fluorine free aldehydes and ketones, i. e., the decomposition of fluorketones with isonitriles and trialkylphosphites. Reactions found by the authors are compared with those found by others: R. Neidlein, F. Ramirex, J. Middletone, and R. V. Lindsey. The authors are stimulated by the work of D. W. Wiley and H. E. Simmons to investigate other conversions of cylindrical phosphoranes and that reaction conditions were nearly the same as those of the American authors. Chemical equations are given throughout the article.

Descriptors :   *FLUORINE COMPOUNDS), (*KETONES, (*REACTION KINETICS, KETONES), WEST GERMANY, DECOMPOSITION, NITRILES, PHOSPHITES, ESTERS, CYCLOHEXANES, ACETONES, IMINES, OXYGEN HETEROCYCLIC COMPOUNDS, PHOSPHORUS HETEROCYCLIC COMPOUNDS.

Subject Categories : Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE