Accession Number : AD0805143

Title :   INVESTIGATION OF THE PARA-ORTHO SHIFT OF HYDROGEN.

Descriptive Note : Technical rept. May 64-Aug 66,

Corporate Author : AIR PRODUCTS AND CHEMICALS INC ALLENTOWN PA

Personal Author(s) : Singleton, A. H. ; Kucirka, J. F. ; Lapin, A.

Report Date : SEP 1966

Pagination or Media Count : 80

Abstract : An investigation of means of promoting the low temperature paraorthohydrogen reaction was conducted. The principal means studied was the synthesis of active heterogeneous catalysts; this approach succeeded in producing a catalyst that was 29 times more active, on a weight basis, than the standard ferric oxide gel material. Studies were conducted to establish a logical engineering model describing the observed kinetic behaviour of this catalyst. It was found that by adjusting the kinetic data to account for temperature gradients within the catalytic reactor and concentration gradients within the catalyst particles that the data closely fit a first order-reversible rate law based on gas phase composition. Means of packaging this catalyst into an efficient catalytic reactor were also studied. As a result of the high catalyst activity, a reactor concept allowing both high flow area, and low bed thickness in the flow direction is required. To satisfy this need a reactor was built in which the catalyst was supported in the form of a thin cylindrical shell, with hydrogen entering the inside of the cylinder and flowing radially through the catalyst shell. The pressure drop obtained with the two units tested was of the order of 10% of that obtained when the catalyst is packaged in an axial flow packed bed reactor of typical length to diameter ratio.

Descriptors :   *MOLECULAR PROPERTIES), (*HYDROGEN, CATALYSTS, THERMAL CONDUCTIVITY, SYNTHESIS(CHEMISTRY), IRON COMPOUNDS, OXIDES, GELS, DYNAMICS, INELASTIC SCATTERING, IONS, MATHEMATICAL MODELS, PARTICLE SIZE, TEST EQUIPMENT, ELECTRODES.

Subject Categories : Atomic and Molecular Physics and Spectroscopy

Distribution Statement : APPROVED FOR PUBLIC RELEASE