Accession Number : AD0809367

Title :   SOME REACTIONS OF OXYGEN ATOMS. VOLUME III: CYCLOPROPANE, CYCLOBUTANE, CYCLOPENTANE, AND CYCLOHEXANE.

Descriptive Note : Rept. for 1 Apr-1 Oct 66,

Corporate Author : AEROSPACE CORP EL SEGUNDO CA LABS DIV

Personal Author(s) : Stuckey, Wayne K. ; Heicklen, Julian

Report Date : NOV 1966

Pagination or Media Count : 24

Abstract : The rate that oxygen atoms react with certain cycloalkanes was determined at 25, 70, and 125 C by the competition for oxygen atoms between a cycloalkane and hexafluoropropene. Oxygen atoms were generated by the mercury-sensitized decomposition of N2O. Then, the known rate-constant expression for C3F6 was used to calculate the rate constant for the oxygen atom-cycloalkane reaction.

Descriptors :   *OXYGEN), (*REACTION KINETICS, CYCLOBUTANES, CYCLOPENTANES, CYCLOHEXANES, SYNTHESIS(CHEMISTRY), MERCURY, PHOTOLYSIS, NITROGEN OXIDES, OXIDATION, FLUORINE COMPOUNDS, GAS CHROMATOGRAPHY, INFRARED SPECTRA.

Subject Categories : Atomic and Molecular Physics and Spectroscopy

Distribution Statement : APPROVED FOR PUBLIC RELEASE