Accession Number : AD0812691

Title :   REACTION OF DIISONITROSOACETONE WITH SULFONYL CHLORIDES.

Descriptive Note : Quarterly rept. no. 4, Apr-Dec 66,

Corporate Author : DELAWARE UNIV NEWARK

Personal Author(s) : Mosher, William A. ; Hively, Richard L.

Report Date : 19 APR 1967

Pagination or Media Count : 43

Abstract : This report contains the results obtained from the study of the color-forming reaction of the secondary amine salts of 1,3-dioximinoacetone and p-toluenesulfonyl chloride. It was found that the reaction of 1,3-dioximinoacetone with p-toluenesulfonyl chloride in the presence of diethylamine, dibutylamine and piperidine yielded the 3-diethylamino-, 3-dibutylammino- and 3-piperidino-4- pyrazolone-1-oxides, respectively. (Author)

Descriptors :   *ACETONES), *OXYCHLORIDES), (*AMINES, (*TOLUENES, CHEMICAL REACTIONS), (*ORGANIC SULFUR COMPOUNDS, ALKANES, PIPERIDINES, ORGANIC OXYGEN COMPOUNDS, CHLORINE COMPOUNDS, SULFONIC ACIDS, NITROGEN HETEROCYCLIC COMPOUNDS, INFRARED SPECTRA, CHROMATOGRAPHIC ANALYSIS, NUCLEAR MAGNETIC RESONANCE.

Subject Categories : Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE