Accession Number : AD0838854

Title :   KINETICS OF AMMONIA SUBSTITUTION INTO TETRACHLOROPALLADATE (II) ION.

Descriptive Note : Master's thesis,

Corporate Author : NAVAL POSTGRADUATE SCHOOL MONTEREY CA

Personal Author(s) : Monk, William Wade

Report Date : JUN 1968

Pagination or Media Count : 66

Abstract : The kinetics of ammonia substitution into tetrachloropalladate ion were studied by ultraviolet spectroscopy. Each pseudo-first-order rate constant was found to obey a two-term rate law. Activation parameters are calculated and the trans and cis effects are discussed.

Descriptors :   (*PALLADIUM COMPOUNDS, SUBSTITUTION REACTIONS), (*COMPLEX COMPOUNDS, REACTION KINETICS), MOLECULAR ISOMERISM, CHEMICAL EQUILIBRIUM, ULTRAVIOLET SPECTROSCOPY, COMPUTER PROGRAMS, TABLES(DATA), THESES, AMMONIA, HEAT OF ACTIVATION.

Subject Categories : Atomic and Molecular Physics and Spectroscopy

Distribution Statement : APPROVED FOR PUBLIC RELEASE