Accession Number : AD0887196

Title :   Electron Acceptor-Electron Donor Interactions. XV and XVI.

Descriptive Note : Final rept.,

Corporate Author : NAVAL WEAPONS CENTER CHINA LAKE CA

Personal Author(s) : Hammond, P. R. ; Burkardt, L. A.

Report Date : JUL 1971

Pagination or Media Count : 18

Abstract : Electron acceptor and electron donor mixtures that display extremely weak or just contact interaction in a number of solvents are examined. The mixtures exhibit simple eutectic phase diagrams and the thermochromic effect is interpreted as a randomized structure in the liquid, whereas the solid is a two-phase aggregate of isolated acceptor and onor crystals. The charge-transfer spectra of solutions of tungsten and molybdenum hexafluorides and iodine heptafluoride in n-hexane and cyclohexane were obtained.

Descriptors :   *MOLECULAR ASSOCIATION), *COMPLEX COMPOUNDS), (*ORGANIC SOLVENTS, (*FLUORIDES, MIXTURES, PHASE STUDIES, ORGANIC NITROGEN COMPOUNDS, TUNGSTEN COMPOUNDS, MOLYBDENUM COMPOUNDS, IODINE COMPOUNDS, ULTRAVIOLET SPECTRA, VISIBLE SPECTRA.

Subject Categories : Atomic and Molecular Physics and Spectroscopy

Distribution Statement : APPROVED FOR PUBLIC RELEASE