Accession Number : AD0902549

Title :   Organic Perchlorates.

Descriptive Note : Final rept. 6 Mar 71-5 Jun 72,

Corporate Author : ROCKETDYNE CANOGA PARK CA

Personal Author(s) : Schack, Carl J.

Report Date : JUN 1972

Pagination or Media Count : 56

Abstract : A variety of new, covalent perchlorates were synthesized, including perfluorinated perchlorates and halofluorocarbon perchlorates. The synthetic approach utilized was a new development and entailed the displacement of halogen from substituted fluorocarbons by the use of chlorine perchlorate. The objective of this program was the utilization of these new halogen perchlorates in the synthesis of new covalent perchlorates. Of principal concern was the demonstration of model reactions and their subsequent use in preparing a variety of new perchlorates. Structural and physico-chemical characterization of the new materials was sought with the aim of uncovering properties pertinent to explosive end product use. (Author)

Descriptors :   (*PERCHLORATES, EXPLOSIVES), (*FLUORINE COMPOUNDS, PERCHLORATES), (*CHLORINE COMPOUNDS, PERCHLORATES), (*CARBON COMPOUNDS, PERCHLORATES), BROMINE COMPOUNDS, IODINE COMPOUNDS, HALOGENATED HYDROCARBONS, SYNTHESIS(CHEMISTRY), VALENCE, CHEMICAL REACTIONS, INFRARED SPECTROSCOPY, NUCLEAR MAGNETIC RESONANCE, COMPLEX COMPOUNDS, ACETONITRILE, MASS SPECTROSCOPY, SOLID ROCKET PROPELLANTS, PHYSICAL PROPERTIES, CHEMICAL PROPERTIES, SUBSTITUTION REACTIONS, ORGANIC COMPOUNDS.

Subject Categories : Organic Chemistry
      Ammunition and Explosives
      Solid Rocket Propellants

Distribution Statement : APPROVED FOR PUBLIC RELEASE