Accession Number : ADA019790

Title :   Calculated Vibration-Rotation Intensities and Line Positions for Ground State Nitric Oxide.

Descriptive Note : Physical sciences research papers,

Corporate Author : AIR FORCE CAMBRIDGE RESEARCH LABS HANSCOM AFB MASS

Personal Author(s) : Billingsley,Frank P. , II

Report Date : 13 NOV 1975

Pagination or Media Count : 183

Abstract : A group of tables is presented listing accurate theoretical line positions and absolute emission intensities for individual multiplet-vibration-rotation transitions in the ground state of nitric oxide. The data covers both intramultiplet and intermultiplet (satellite band) transitions for vibrational levels up to v = 20, and total angular momentum states up to J = 33.5 in the fundamental (delta v = 1) and first overtone (delta v = 2) manifolds. The calculated intensities were obtained with an accurate representation of the electronic dipole moment function of nitric oxide and wavefunctions generated from a numerical RKR potential taking full account of rotation-vibration coupling and spin-uncoupling. In addition to the detailed line emission data, thermally averaged vibrational band intensities are provided for application to low resolution studies. (Author)

Descriptors :   *Nitrogen oxides, *Molecular vibration, Molecular rotation, Ground state, Emission, Dipole moments, Wave functions, Eigenvectors, Infrared radiation, Tables(Data)

Subject Categories : Quantum Theory and Relativity

Distribution Statement : APPROVED FOR PUBLIC RELEASE