Accession Number : ADA117079

Title :   Exploratory High Pressure Chemistry.

Descriptive Note : Final technical rept. 1 Apr 79-31 Mar 82,

Corporate Author : CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY

Personal Author(s) : Gladysz,John A

PDF Url : ADA117079

Report Date : 31 Mar 1982

Pagination or Media Count : 9

Abstract : A novel 1,3-silatropic shift was observed in the acylation of a silylated iron anion. A high yield cycloaddition of allyl iron complexes to olefins under pressure was carried out. This reaction constitutes a relatively rare example of a 3 plus 2 cycloaddition to give a 5-membered carbocyclic ring. It was found that migratory insertion reactions of transition metal alkyls can be effected by the application of pressure. (Author)

Descriptors :   *Acylation, *Cyclic compounds, *High pressure, *Migration, Iron compounds, Anions, Alkyl radicals, Metal complexes, Reaction kinetics, Addition reactions

Subject Categories : Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE